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Corrosion Irritation: Dermal: 10196-18-6 Skin - Rabbit Result : Severe skin irritation - 24 h Ocular: 10196-18-6 cooking salt) activates the etch by diminishing the bond with water. Wear nitrile rubber gloves, laboratory coat, and eye protection. WebExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 Radioactive Wastes. The availability of these disposal methods varies depending on where you live. State and local disposal regulations may differ from federal disposal regulations. Wear protective gloves/protective clothing/eye protection/face protection. While this can sometimes be time consuming, it can often be more environmentally and economically friendly than discarding the waste in one manner or another is. Bis(ethylenediamine)copper(II) perchlorate, N-(1-Naphthyl)ethylenediamine dihydrochloride, http://woelen.homescience.net/science/chem/exps/rules.html, http://www.atsdr.cdc.gov/toxprofiles/tp187-c5.pdf, http://link.springer.com/article/10.1007%2FBF02318626, http://pubs.rsc.org/en/Content/ArticleLanding/2007/EM/b709571f#!divAbstract, Chemical Technology and Emission Control, 2012, M.B. It is used in making rayon, as a wood preservative, and as an analytical reagent. Keep the copper carbonate for other experiments or bin it as it is basically inert. Results in acidic vapors, extremely dangerous and corrosive, Toxic to wildlife and corrosive to minerals, DON'T! Alkali hydroxides can be left in open air to absorb carbon dioxide as well as corrosive and unpleasant gases, forming carbonates and salts. WebTests showed that a solution made up from equal parts of copper sulfate and sodium chloride (i.e. Webpersonnel. Copper and Zinc have specific discharge limits Decomposes at high temperatures to yield carbon oxides, water vapors, soot, VOCs, etc. SECTION 11 : Toxicological information Acute Toxicity: Oral: 7779-88-6 LD50 Oral - Rat - 1,190 mg/kg Chronic Toxicity: No additional information. Web2. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. 6.4 Reference to other sections For disposal see section Sweep up spill and place in sealed bag or container for disposal. EXALGO. It is a good idea to take these to a proper waste disposal facility. For the disposal of large amounts of hazardous reagents or for special reagents, ask the help of professional hazardous chemical disposal entities. The amount-of-substance concentration of this volumetric solution is determined with standardized titriplex-III solution (article number 1.08431). It is used in the production of rayon, as a feed supplement, and as a fertilizer ingredient. SDS (Sodium Dodecyl Sulfate) (up to 1-25% concentration) Sodium carbonate/Sodium hydrogen carbonate. Anhydrous zinc sulfate is a colorless crystalline solid. Hydration, followed by recycling, dumping in trash, ground, etc. All forms are soluble in water. Use water spray to keep fire-exposed containers cool. Zinc Sulfatereacts violently with PHOSPHORUS and FINELY DIVIDED ALUMINUM or MAGNESIUM. Zinc Sulfate is not compatible with STRONG BASES (such as SODIUM HYDROXIDE and POTASSIUM HYDROXIDE). Breaks down rapidly in the environment due to air and microorganisms, yielding sulfides and sulfates. Waste containing cyanide, either from gold refining or from organic extractions of alkaloids from cyanide containing plants, must be neutralized with bleach or hydrogen peroxide, to turn them into less harmful cyanates. Bleach (best bet); hydrogen peroxide; oxygen; ozone; Extremely toxic for all organisms, used to kill pests, Neutralize it first, good source of phosphorus, unless contaminated, Deadly to small animals; excess in water bodies may cause algal bloom, Suspension of calcium hydroxide, sodium thiosulfate, cooled; PBr, Breaks down to bromine, hydrogen bromide, phosphorus tribromide and phosphorous acids in the presence of air/moisture, Corrosive and deadly to all wildlife; Lowers soil pH; Corrosive to rocks, soil, Suspension of calcium hydroxide, cooled; PCl, Boils and breaks down to chlorine, hydrogen chloride and phosphorous acids in the presence of air/moisture, Will volatilize at very high temperatures, No, reaction with water is highly exothermic and may generate acidic steam. Dispose of contents/container in accordance with local/regional/national/international regulation. (Zinc sulfate) Transport hazard class(es) Class: 9 Miscellaneous dangerous substances and articles Packing group:III Environmental hazard: Transport in bulk: Name: Marine Pollutant Piranha solution is an excellent material for the disposal of organic compounds. NaOH, Decomposes to release nitrogen/chlorine oxides and oxygen, Aqueous base; percarbonates can also be used to remove nitric oxide; multiple washings may be required, Decomposes, giving off nitrogen oxide and chlorine/HCl fumes, Highly corrosive and toxic to all organisms and materials, Careful addition to crushed ice, followed by neutralization with a diluted base, Deadly and extremely corrosive to all organisms, Diluted and hydrolyzed; Careful and controlled pyrolysis, Any base, hydroxide, carbonate, bicarbonate; percarbonates can also be used, Decomposes, giving off nitrogen oxide fumes, Corrosive to organisms and rocks; salts somewhat toxic to animals, Gentle reduction with various reducing agents, Breaks down to nitrogen and oxygen at high temperatures, Low toxicity to wildlife, may induce light narcotic effects and laughing sensation in some organisms, Mixed with a more flammable solvent, followed by incineration, Safe, occurs naturally in citrus fruit peels, Pyrolysis; diluted and poured down the drain, Decomposes on heating to release carbon oxides and various organic compounds, May pose a threat to wildlife in large amounts, Reduced with hydrogen or another reducing agent, Neutralization with any oxide, hydroxide, carbonate, followed by pyrolysis, Releases carbon oxides and water vapor at high temperature, Toxic to wildlife; Small amounts occur in some plants, Disolving it in large amounts of water, followed by neutralization with any oxide, hydroxide, carbonate, Toxic and corrosive to wildlife and environment, Any compound easily oxidizable that does not ignite, such as carbon monoxide, activated charcoal, Accelerates the decomposition of ozone, but not enough, Dangerous to wildlife, may oxidize various gaseous compounds, contributing to the acid rain; In the upper atmosphere it acts as UV shield, Will burn if ignited, releasing carbon oxides, water vapors and soot, Excess paper is harmful for environment, unless composted first, Wax, both solid and molten, floats on water bodies and may inhibit the cellular breathing of many organisms, Mixed with a flammable solvent and incinerated, Gives off carbon oxides, water vapors, aldehydes, Low toxicity to aquatic life; Classified as biodegradable, Oxidation with Fenton's reagent; Mixed with a flammable solvent and incinerated; Reduction with powdered iron, Gives off carbon oxides, water vapors, soot, Displays relative low toxicity to aquatic life; PETN undergoes safe biodegradation, Flammable, releases carbon oxides, water vapor when burned in air, Bicarbonates, carbonates, bases, oxides; neutralized solution can be safely poured down the drain; valeric salts can also be pyrolyzed in a kiln, Flammable (high concentrations, >86 C), no dangerous combustion products, though the smoke will have a rancid smell, Dangerous for wildlife and aquatic life in large concentrations, Dilution in water, followed by neutralization with a base; iron oxide can be added to decompose hydrogen peroxide; can be poured down the drain afterwards, May explode at high temperatures, at high concentrations, Toxic and corrosive to wildlife, both animals and plants, Neutralization with potassium, calcium bases, followed by reduction with metallic iron under UV light in the absence of air, Leads to decomposition, resulting in manganese dioxide slag, The resulting manganese dioxide from the decomposition can be toxic if ingested by animals, Strong oxidizer, it is dangerous and toxic to small organisms, Oxidation with Fenton's reagent or piranha solution, followed by neutralization and poured down the drain, Gives off carbon oxides, water vapors, soot, VOCs, PAHs, nitrogen, Dangerous to environment, very toxic to aquatic life, Flammable if preheated, gives off carbon dioxide, soot and water vapors, Gives off carbon oxides, water vapors, soot and VOCs, Dilute it with plenty of water before release, Dangerous to environment in large amounts, Not always required, may be strongly diluted and poured down the drain, Breaks down to carbon oxides, water vapors, soot; may give off aromatic vapors, Low toxicity, may occur naturally in small amounts, Oxidation with Fenton's reagent; Incineration, best done with an afterburner, Flammable, burns in air to release carbon oxides, water vapors, soot, VOCs, Toxic to wildlife and very dangerous to aquatic life, as well as soil. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. Aqueous solutions are acidic. Small quantities. Corrosive and dangerous on direct contact with wildlife; Reaction with water will lead to phosphoric acid, highly corrosive and dangerous. Before discarding waste, think about what all it contains, and if there is some way that it could be used. Acidic salts, such as ZINC SULFATE, are generally soluble in water. The decomposition is highly exothermic and the resulting smoke is very dangerous. Just make sure to dilute the bases first. Web site owner: Breaks down yielding phosphine, phosphorus oxides and nitrogen oxides. WebDispose of it by rinsing with water, dissolving in excess dilute sulfuric acid and washing the resulting zinc sulfate solution down the sink. This compound is insoluble in water and acids, showing little reactivity. Bleach can be used to neutralize the compound, May pose a threat to wildlife in large amounts due to its sodium content, Decomposes on heating to release carbon monoxide, May pose a threat to wildlife in large amounts since it's a sodium salt; Occurs naturally as mineral, Slow addition to diluted solution of phosphoric acid, A reducing agent like sodium thiosulfate or sulfite; Generally not required though, Decomposes to release water vapors and oxygen, leaving behind sodium borate, Hydrogen peroxide in harmful for organisms; High levels of sodium and boron are toxic for plants, Any acid; Iron(III) oxide or manganese dioxide can also be added for complete neutralization; Generally not required though, Decomposes to release water vapors and oxygen, leaving behind sodium carbonate, Hydrogen peroxide in harmful for organisms; High levels of sodium are toxic for plants, Burns in a mixture with flammable materials, Decomposes to manganese dioxide and sodium oxide/hydroxide at high temperatures, Hydrolyzes in water to sulfuric acid; addition of a base to neutralize the acid, Oxidizer, harmful; excess sodium harmful for plants, Only in places without plant or animal life (construction sites, quarries, etc. If the mixture of sodium zincate solution and zinc is cloudy, allow to cool, and then filter off the zinc to leave a clear filtrate. Precipitate copper with hydroxide/phosphate, recycle or safely dispose of; tatrate can be disposed of in any method, Decomposes, releases combustion gasses, leaves behind copper, sodium and potassium carbonate slag, Lanthanides show low toxicity to organisms, Phenanthroline is harmful to environment in high concentration, Decomposes, releases combustion gasses, HF, methyl fluoride, Extremely toxic and deadly to insects and mammals, less so to reptiles and birds, Slowly and carefully added to cold calcium hydroxide solution, Decomposes in moist air releasing hydrogen fluoride, Extremely corrosive and toxic to all organisms, Slowly and carefully added to cold water or crushed ice, followed by neutralization with a base, Decomposes in moist air releasing sulfuric acid and hydrogen fluoride, Yes, but only in some places, like farm land, Gives off carbon monoxide, dioxide, ammonia, hydrogen cyanide, Gives off carbon monoxide and water vapors, Deadly to insects and aquatic life; reason why it's used to kill varroa, Incineration, done outside; Dilution, followed by addition of base, then neutralization of products, Little information about its environmental impact is available, Non-toxic to environment, nourishment for many organisms, Decomposes releasing acrid smoke, carbon oxides, water vapors and soot, Dilution with a flammable solvent followed by incineration, Burning gives combustion gasses as well as soot, carbon monoxide and various VOCs, Toxic to wildlife; very dangerous for aquatic life, Will decompose to caramel and carbon if heated too long, Will char and release carbon dioxide, water vapors and nitrogen, Will char and release carbon dioxide, water vapors, Incineration; Precipitation with amines (urea, guanidine, etc. It's not recommended to use zinc compounds obtained from technical sources as zinc supplements for soil or livestock, as it may contain traces of heavy metals, such as cadmium. NaOH; Strong dilution; Oxidation with Fenton's reagent, Generates carbon oxides, water vapor, soot, sulfur oxides and HCl fumes, Incineration; Sodium pyrosulfite; L-cysteine, Generates carbon oxides and water vapors; some will evaporate when heated, Dilution in a more flammable solvent, followed by incineration; Oxidation with Fenton's reagent, Gives off carbon monoxide, dioxide, ammonia, acetonitrile, hydrogen cyanide, Addition to water followed by heating, yielding acetic acid and ammonium chloride, Anhydrous conditions yields ammonium chloride and acetonitrile; In presence of water acetic acid and ammonium chloride are formed, Flammable (high concentrations), no dangerous combustion products, Safe, biodegradable; avoid dumping large amounts, acidifies soil, Flammable, no dangerous combustion products, Biodegradable; avoid dumping large amounts, acidifies soil, Oxidation/incineration, reducing, photolysis, Biodegradable, though not advised for large amounts, Fenton's reagent; Aqueous solution of excess sodium hydroxide, All treatments give some hydrogen cyanide fumes, Toxic to all life due to its cyanide/nitrile group; does not quickly break down in environment, Mixed with a more flammable solvent and incinerated, Generates smoke, carbon dioxide and water vapors, Relative safe, biodegradable; Occurs naturally in small amounts, Burn products include hydrogen chloride which is corrosive, Extremely toxic and corrosive to organisms and environment, Gives off carbon dioxide and water vapors, Addition of a base, which causes polymerization, Burns in the presence of oxygen releasing carbon oxides, water, and various other organic products, Burning, dumping in ground; Desorption by heating it to high temperature and reuse, Unless it adsorbed dangerous volatile compounds or heavy metals, it can be used as a fertilizer (powdered form); Less effective as beads or pellets, Safe, biodegradable; nourishment for many organisms, Diluted with a flammable solvent, like ethanol or acetone and burned; Epoxidation and hydrolysis to glycerol, Loses magnetism when heated and melts at high temperatures, Nickel and cobalt are harmful for the environment, Generates smoke, carbon dioxide and water vapor, Treatment with water, precipitation with a base, No effect; Water solutions however will give off hydrogen chloride vapors, Treatment with water, precipitation with a base; recycling of iodine, No effect; Water solutions however will give off hydrogen iodide and iodine vapors, Incineration outside; Treatment with water, recovery of isopropanol and aluminium oxide/hydroxide or incineration of isopropanol, Melts and decomposes to give various ketones and isopropanol which may ignite; leaves behind alumina residue, Increases level of aluminium from soil, corrosive and harmful to organisms, Pyrolysis; Aqueous ammonia or alkaline hydroxide solution, Not always required, can be dumped in trash, Increases level of aluminium in soil, toxic to animals in large quantities, Burns in air, releasing fumes of phosphorus pentoxide and aluminium oxide, as well as traces of phosphine if any moisture is present, Releases phosphine gas on contact with water, which is deadly to organisms, Releases sulfur oxides at high temperature, Dilute it first; neutralization with a base first is recommended, Increases the aluminium concentration in soil and water, lowers pH, Releases hydrogen sulfide on contact with water, which is toxic to organisms, Burns, may detonate in the presence of metallic impurities, like copper, brass, While ammonium nitrate is a good nitrogen source for plants, TNT is very harmful for wildlife, Not required, can be discarded in any way, Pyrolysis gives nitrogen and carbon oxides, Not required, can be dumped in ground; Pyrolysis done outside, Pyrolysis gives nitrogen, water and carbon/nitrogen oxides, Little is known about its environmental impact, Not required, can be dumped in ground; Careful and controlled pyrolysis, Pyrolysis gives nitrogen, water and carbon/nitrogen oxides; may explode at high temperatures, Safe, nitrogen source for plants; Guanidine derivates occur in guano, Burns, may detonate in the presence of metallic impurities, like copper, While ammonium nitrate is a good nitrogen source for plants, the aluminium, TNT and other impurities present are harmful for wildlife, At high concentrations may generate nitrogen oxides, Not possible (gaseous), safe to pour (as solution), Not possible (gaseous), safe to pour (as solution); Good nitrogen source for plants, Slowly volatilizes and explodes at 400 C releasing nitrogen, hydrogen and ammonia gasses, Decomposes on heating releasing carbon dioxide, ammonia fumes and water vapors, Neutralize it with ammonia; can then poured down the drain, Decomposes to release sulfur oxides and ammonia, Yes, though recommended to neutralize first, Acidic, but once neutralized good nitrogen and sulfur source for plants, While it can be diluted and poured down the drain, it's recommended to neutralize it first; hydrogen peroxide and ammonia can be used to safely neutralize it, Decomposes to release sulfur dioxide and ammonia, Oxidation of aqueous ammonium bisulfite to bisulfate can reduce the amount of dissolved oxygen from water bodies and will lower water pH, Decomposes on heating releasing nitrogen, water, oxygen and hydrogen chloride, sometimes explosively, Decomposes on heating releasing ammonia and hydrogen chloride, Safe, good fertilizer (nitrogen source); May prove unsuitable to chloride sensitive plants, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid, at acidic pH, Decomposes, the famous volcano reaction, releasing nitrogen gas, water vapors, fine particulates of unburnt ammonium chromate, leaving behind Cr(III) oxide, Cr(VI) ions are carcinogenic and very toxic to organisms, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid at acidic pH, Decomposes, the famous volcano reaction, releasing nitrogen gas, water vapors, fine particulates of unburnt ammonium dichromate, leaving behind Cr(III) oxide, Not required; Slaked lime can be used to precipitate calcium phosphate, Safe, good fertilizer (nitrogen and phosphorus source), Decomposes on heating to release nitrogen, water and oxygen; may explode if heated too high, While it may be a good fertilizer, its environmental effects are unknown, Decomposes in several steps, releasing ammonia, water, cyanogen, ferric oxide, in air, Low toxicity, environmental effects unknown, Alkali hydroxide, carbonate, sulfate; heating in the presence of a base, Decomposes on heating to release ammonia, carbon monoxide, hydrogen cyanide and water, Alkali hydroxide, carbonate, sulfate; Dilution, poured down the drain, Decomposes on heating to release ammonia, water, leaving behind MoO, Diluted cooled hydrogen peroxide solution, Harmful to organisms, especially aquatic ones, Safe, good fertilizer (nitrogen, iron and sulfur source); May cause algal bloom in water bodies however, Safe, good fertilizer (nitrogen source); May cause algal bloom in water bodies however, Alkali hydroxides; strong dilution followed by heating; will slowly decompose even at room temperature, so you may leave it in a safe area and let it decompose, Decomposes or detonates, releasing nitrogen and water vapors, Decomposes quickly in environment, especially at low pH, Alkali hydroxide, carbonate, sulfate; pyrolysis in the presence of a base, Decomposes on heating to release ammonia, carbon monoxide, oximide, hydrogen cyanide and water vapors, May pose a threat to wildlife in large amounts; Occurs naturally in guano, Reduction with metallic iron under UV light in the absence of air; Heating perchlorate at 200 C with metallic iron for several hours, Decomposes to release nitrogen, water vapors, oxygen and hydrogen chloride, Dissolution in water, followed by reduction with sulfur dioxide or sodium sulfite, thiosulfate or metabisulfite, Detonates above 60-110 C, releasing nitrogen, water vapors and a smoke of manganese dioxide, Strong oxidizer and explosive, hazardous for wildlife, Pyrolysis, hydrolysis, various reducing agents, Decomposes at 120 C releasing sulfur and nitrogen oxides, oxygen and ammonia, Not required; Strong dilution is sufficient, Decomposes on heating to release ammonia, sulfur dioxide, sulfuric acid vapors, Considered to be environmentally friendly due to its degradation to non-harmful residues, Not required; Calcium hydroxide can be used to precipitate calcium sulfate, Safe, good fertilizer (nitrogen and sulfur source); slightly lowers the soil pH, Decomposes releasing hydrogen sulfide and ammonia, Extremely toxic for wildlife; Dangerous for the environment (DSD), Not required, simply pour down the drain; Bleach or hydrogen peroxide can be used if desired, Oxidation of aqueous ammonium sulfite to sulfate can reduce the amount of dissolved oxygen from water bodies; otherwise, safe, used as fertilizer, Precipitation with sodium hydroxide to less sodium fluorides, Emits very toxic fumes of hydrogen fluoride, nitrogen oxides and ammonia, Dilute then pour down the drain; Bleach or hydrogen peroxide can be used if desired, Decomposes to release sulfur dioxide, ammonia, water vapors, May be harmful for aquatic life; safe, used as fertilizer, While ammonium nitrate is a good nitrogen source for plants, the fuel oil (FO) from its composition is harmful for wildlife, Gives off carbon oxides, soot, nitrogen and or nitrogen oxides and water vapor, Dilution with a solvent, followed by incineration; Oxidation with an oxidizing solution, like Fenton's reagent, Gives off carbon oxides, soot and water vapor, While ammonium nitrate is a good nitrogen source for plants, nitromethane and methanol may be harmful for wildlife, Sublimes and decomposes, releasing carbon oxides, water vapors, soot, anilline, Mixed with a more flammable solvent and safely incinerated; Controlled oxidation with Fenton's reagent.
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